Organic Synthesis with Palladium Compounds

Organic Synthesis with Palladium Compounds
Author: Jiro Tsuji
Publisher: Springer Science & Business Media
Total Pages: 221
Release: 2012-12-06
Genre: Science
ISBN: 3642674755

Around 30 years ago the transition metal chemistry received great impulses. In the focus have been reactions of nickel and cobalt and herein especially their carbonyls. Also industrial processes have been developed. When the technical oxidation of ethylene with palladium chloride had been discovered, and a great number oflaboratory reactions, many groups have turned towards this subject. Apart from two important industrial processes - acetaldehyde and vinylacetate from ethylene - a great number of conversions and catalytic reactions with palladium compounds have been researched. Their mechanisms have been cleared up and have con tributed to a better understanding of the complex chemistry of palladium. Last but not least these reactions have also served for more understanding of organic transition metal compounds and catalyses in general. Numerous conventional reactions appear today in a different light. The effects of co-

Palladium in Organic Synthesis

Palladium in Organic Synthesis
Author: Jiro Tsuji
Publisher: Springer Science & Business Media
Total Pages: 348
Release: 2005-07-06
Genre: Science
ISBN: 9783540239826

with contributions by numerous experts

Handbook of Organopalladium Chemistry for Organic Synthesis

Handbook of Organopalladium Chemistry for Organic Synthesis
Author: Ei-ichi Negishi
Publisher: John Wiley & Sons
Total Pages: 1657
Release: 2003-11-24
Genre: Science
ISBN: 0471473812

Organized to provide maximum utility to the bench synthetic chemist. The editor is well-known for his work in exploring, developing, and applying organopalladium chemistry. Contributors include over 24 world authorities in the field.

Palladium Reagents and Catalysts

Palladium Reagents and Catalysts
Author: Jiro Tsuji
Publisher: Wiley
Total Pages: 670
Release: 2004-06-25
Genre: Science
ISBN: 9780470850336

Jiro Tsuji, one of the pioneers in this field of organic synthesis, provides synthetic organic chemists with a remarkable overview of the many applications of organopalladium chemistry. Tsuji discusses the recent developments in the field as well as the explosive growth over the last five years. Highlighting the most recent discoveries in this rapidly expanding field, the book; Focuses on new aspects of organopalladium chemistry, putting emphasis on synthetic applications Investigates the new perspectives on the synthetic uses of contemporary organopalladium chemistry This volume, together with Innovations in Organic Synthesis, Tsuji's previous title, provides complete coverage of over 40 years of organopalladium chemistry. Palladium Reagents and Catalysts: New Perspectives for the 21st Century is an essential reference source and companion for students, and both industrial and academic research chemists working in organic synthesis, particularly on synthesis of natural products and medicinal compounds. Those studying development of new synthetic methodology and organometallic chemistry will also find this book valuable.

Palladium Assisted Synthesis of Heterocycles

Palladium Assisted Synthesis of Heterocycles
Author: Navjeet Kaur
Publisher: CRC Press
Total Pages: 444
Release: 2019-05-01
Genre: Medical
ISBN: 1351242601

This book is a compilation of the recent applications of palladium catalysts in organic synthesis. The book demonstrates that it is a highly dynamic research field. This methodology has emerged as a powerful tool for the efficient and chemoselective synthesis of heterocyclic molecules. In the past few years, several strategies have been pointed out to pursue more efficient, sustainable, and environment friendly chemical processes. Among those strategies, catalysis and the design of new processes that avoid the use of toxic reagents have been the focus of intense research.

Application of Transition Metal Catalysts in Organic Synthesis

Application of Transition Metal Catalysts in Organic Synthesis
Author: L. Brandsma
Publisher: Springer Science & Business Media
Total Pages: 349
Release: 2012-12-06
Genre: Science
ISBN: 3642603289

Homogeneous catalysis is an important strategy for the synthesis of high-valued chemicals. L. Brandsma has carefully selected and checked the experimental procedures illustrating the catalytic use of copper, nickel, and palladium compounds in organic synthesis. All procedures are on a preparative scale, make economic use of solvents and catalysts, avoid toxic substances and have high yields.

Side Reactions in Organic Synthesis

Side Reactions in Organic Synthesis
Author: Florencio Zaragoza Dörwald
Publisher: John Wiley & Sons
Total Pages: 389
Release: 2006-03-06
Genre: Science
ISBN: 3527604987

Most syntheses in the chemical research laboratory fail and usually require several attempts before proceeding satisfactorily. Failed syntheses are not only discouraging and frustrating, but also cost a lot of time and money. Many failures may, however, be avoided by understanding the structure-reactivity relationship of organic compounds. This textbook highlights the competing processes and limitations of the most important reactions used in organic synthesis. By allowing chemists to quickly recognize potential problems this book will help to improve their efficiency and success-rate. A must for every graduate student but also for every chemist in industry and academia. Contents: 1 Organic Synthesis: General Remarks 2 Stereoelectronic Effects and Reactivity 3 The Stability of Organic Compounds 4 Aliphatic Nucleophilic Substitutions: Problematic Electrophiles 5 The Alkylation of Carbanions 6 The Alkylation of Heteroatoms 7 The Acylation of Heteroatoms 8 Palladium-Catalyzed C-C Bond Formation 9 Cyclizations 10 Monofunctionalization of Symmetric Difunctional Substrates

Palladium Reagents and Catalysts

Palladium Reagents and Catalysts
Author: Jiro Tsuji
Publisher:
Total Pages: 596
Release: 1995
Genre: Science
ISBN:

Basic chemistry of organopalladium compounds; Classification of the reactions involving Pd(II) compounds and Pd(O) complexes.

Metal-catalyzed Cross-coupling Reactions

Metal-catalyzed Cross-coupling Reactions
Author: François Diederich
Publisher: John Wiley & Sons
Total Pages: 540
Release: 2008-07-11
Genre: Science
ISBN: 3527612203

Carbon-carbon bond forming reactions are arguably the most important processes in chemistry, as they represent key steps in the building of complex molecules from simple precursors. Among these reactions, metal-catalyzed cross-coupling reactions are extensively employed in a wide range of areas of preparative organic chemistry, ranging from the synthesis of complex natural products, to supramolecular chemistry, and materials science. In this work, a dozen internationally renowned experts and leaders in the field bring the reader up to date by documenting and critically analyzing current developments and uses of metal-catalyzed cross-coupling reactions. A particularly attractive and useful feature, that enhances the practical value of this monograph, is the inclusion of key synthetic protocols, in experimental format, chosen for broad utility and application. This practice-oriented book can offer the practitioner short cuts to ensure they remain up-to-date with the latest developments.