Spectroscopic Properties of Rare Earths in Optical Materials

Spectroscopic Properties of Rare Earths in Optical Materials
Author: Guokui Liu
Publisher: Springer Science & Business Media
Total Pages: 567
Release: 2006-01-29
Genre: Science
ISBN: 3540282092

Aimed at researchers and graduate students, this book provides up-to-date information about the electronic interactions that impact the optical properties of rare earth ions in solids. Its goal is to establish a connection between fundamental principles and the materials properties of rare-earth activated luminescent and laser optical materials. The theoretical survey and introduction to spectroscopic properties covers electronic energy level structure, intensities of optical transitions, ion-phonon interactions, line broadening, and energy transfer and up-conversion. An important aspect of the book lies in its deep and detailed discussions of materials properties and the potential of new applications such as optical storage, information processing, nanophotonics, and molecular probes that have been identified in recent experimental studies. This volume will be a valuable reference book on advanced topics of rare earth spectroscopy and materials science.

Tables for Emission Spectrographic Analysis of Rare Earth Elements

Tables for Emission Spectrographic Analysis of Rare Earth Elements
Author: Ch Kerekes
Publisher:
Total Pages: 58
Release: 1964
Genre: Earths, Rare
ISBN:

"This volume contains the results of the evaluations for all the metallic elements and binary alloy systms for which thermodynamic data were available." Sources of data given. Systems and author indexes.

Lasers and Excited States of Rare Earths

Lasers and Excited States of Rare Earths
Author: Renata Reisfeld
Publisher: Springer Science & Business Media
Total Pages: 235
Release: 2012-12-06
Genre: Science
ISBN: 3642666965

The possibility of stimulated light emission was discussed by Einstein in 1917, eight years before the quantum-mechanical description of energy levels of many-electron systems. Though it is imperative to use samples having optical properties greatly different from the stan dard continuous spectrum of opaque objects ("black body" radia tion) it is not always necessary to restrict the study to monatomic entities. Thus, spectral lines can be obtained (in absorption and in emission) from lanthanide compounds, containing from one to thir teen 4f electrons going from trivalent cerium to ytterbium, that are nearly as sharp as the ones from gaseous atoms. However, the presence of adjacent atoms modifies the simple picture of an isolated electron configuration, and in particular, it is possible to pump excited levels efficiently by energy transfer from species with intense absorption bands, such as the inter-shell transitions of other lanthanides and of thallium(I), lead(II) and bismuth(III) or the electron transfer bands of the uranyl ion or other complexes. On the other hand, it is possible to diminuish the mUlti-phonon relaxation (competing with sharp line luminescence) by selecting vitreous or crystalline materials with low phonon energies. Obviously, one cannot circumvent the conservation of energy by lasers, but they may have unprecedented consequences for the future by allowing nuclear fusion of light elements, effects of non-linear optics and time-resolved spectroscopy, besides the more conventional applications of coherent light beams with negligible angular extension.

Extractive Metallurgy of Niobium

Extractive Metallurgy of Niobium
Author: A.K. Suri
Publisher: Routledge
Total Pages: 272
Release: 2017-11-13
Genre: Science
ISBN: 1351448978

The growth and development witnessed today in modern science, engineering, and technology owes a heavy debt to the rare, refractory, and reactive metals group, of which niobium is a member. Extractive Metallurgy of Niobium presents a vivid account of the metal through its comprehensive discussions of properties and applications, resources and resource processing, chemical processing and compound preparation, metal extraction, and refining and consolidation. Typical flow sheets adopted in some leading niobium-producing countries for the beneficiation of various niobium sources are presented, and various chemical processes for producing pure forms of niobium intermediates such as chloride, fluoride, and oxide are discussed. The book also explains how to liberate the metal from its intermediates and describes the physico-chemical principles involved. It is an excellent reference for chemical metallurgists, hydrometallurgists, extraction and process metallurgists, and minerals processors. It is also valuable to a wide variety of scientists, engineers, technologists, and students interested in the topic.

Complexes of the Rare Earths

Complexes of the Rare Earths
Author: Shyama P. Sinha
Publisher: Elsevier
Total Pages: 214
Release: 2013-10-22
Genre: Science
ISBN: 1483156796

Complexes of the Rare Earths focuses on the properties, characteristics, and reactions of rare earth complexes. The book first offers information on the complexes of rare earths and coordination through nitrogen of the donors. Discussions focus on the factors influencing the formation of complexes, phenanthroline, phthalocyanine, pyridine, quinolone, and urotropine. The text then elaborates on coordination through oxygen of the donors, including acids, alcohols, adducts, aldehydes, and ketones. The publication takes a look at coordination through both oxygen and nitrogen of the donors; coordination through atoms other than nitrogen and oxygen; and spectral characteristics of rare earths and their complexes. Topics include crystal field splitting, intensification or hypersensitivity of absorption bands, electron transfer spectra and optical electronegativity, and nephelauxetic effect. The text further ponders on luminescence of rare earths in chelates and in different environments, laser and applicability of rare earths as laser materials, and rare earths and the actinides. The book is a dependable source material for readers interested in the complexes of rare earths.

Nanostructured and Advanced Materials for Applications in Sensor, Optoelectronic and Photovoltaic Technology

Nanostructured and Advanced Materials for Applications in Sensor, Optoelectronic and Photovoltaic Technology
Author: Ashok K. Vaseashta
Publisher: Springer Science & Business Media
Total Pages: 446
Release: 2005-09-01
Genre: Technology & Engineering
ISBN: 9781402035609

The principal aim of this NATO Advanced Study Institute (ASI) "Nanostructured and Advanced Materials for Applications in Sensor, Optoelectronic and Photovoltaic Technology" was to present a contemporary overview of the field of nanostructured and advanced electronic materials. Nanotechnology is an emerging scientific field receiving significant worldwide attention. On a nanometer scale, materials or structures may possess new and unique physical properties. Some of these are now known to the scientific community, but there may well be many properties not yet known to us, rendering it as a fascinating area of research and a suitable subject for a NATO ASI. Yet another aspect of the field is the possibility for creating meta-stable phases with unconventional properties and the ultra-miniaturization of current devices, sensors, and machines. Such nanotechnological and related advanced materials have an extremely wide range of potential applications, viz. nanoscale electronics, sensors, optoelectronics, photonics, nano-biological systems, na- medicine, energy storage systems, etc. This is a wide-ranging subject area and therefore requires the formation of multi-disciplinary teams of physicists, chemists, materials scientists, engineers, molecular biologists, pharmacologists, and others to work together on the synthesis and processing of materials and structures, the understanding of their physical properties, the design and fabrication of devices, etc. Hence, in formulating our ASI, we adopted an int- disciplinary approach, bringing together recognised experts in the various fields while retaining a level of treatment accessible to those active in specific individual areas of research and development.

Geochemistry and Mineralogy of Rare Earth Elements

Geochemistry and Mineralogy of Rare Earth Elements
Author: Bruce R. Lipin
Publisher: Walter de Gruyter GmbH & Co KG
Total Pages: 360
Release: 2018-12-17
Genre: Science
ISBN: 1501509039

Volume 21 of Reviews in Mineralogy treats a short course on the rare earth elements to about 80 participants in San Francisco, California, December 1-3, 1989, just prior to the fall meeting of the American Geophysical Union. Contents: Cosmochemistry of the Rare Earth Elements: Condensation and Evaporation Processes Radiogenic Isotope Geochemistry of Rare Earth Elements Partitioning of Rare Earth Elements between Major Silicate Minerals and Basaltic Melts An Approach to Trace Element Modeling Using a Simple Igneous System as an Example Rare Earth Elements in Upper Mantle Rocks Rare Earth Elements in Metamorphic Rocks Rare Earth Elements in Sedimentary Rocks: Influence of Provenance and Sedimentary Processes Aqueous Geochemistry of Rare Earth Elements Rare Earth Elements in Lunar Materials Compositional and Phase Relations among Rare Earth Element Minerals Economic Geology of Rare Earth Minerals Cathodoluminescence Emission Spectra of Rare Earth Element Activators in Minerals