Advanced Free Radical Reactions for Organic Synthesis

Advanced Free Radical Reactions for Organic Synthesis
Author:
Publisher: Elsevier
Total Pages: 271
Release: 2004-01-14
Genre: Science
ISBN: 0080524257

Free radical reactions have become increasingly important and a very attractive tool in organic synthesis in the last two decades, due to their powerful, selective, specific, and mild reaction abilities. Advanced Free Radical Reactions for Organic Synthesis reviews information on all types of practical radical reactions, e.g. cyclizations, additions, hydrogen-atom abstractions, decarboxylation reactions. The book usefully provides experimental details for the most important reactions as well as numerous references to the original literature. By covering both the fundamentals and synthetic applications it is therefore suitable for both new and experienced researchers, chemists, biochemists, natural product chemists and graduate students. This title is the definitive guide to radical chemistry for all scientists. Introduces and reviews the use of radicals to perform synthetic transformations Practical details are provided for the most important methods Numerous references to the original literature

Free Radical Chain Reactions in Organic Synthesis

Free Radical Chain Reactions in Organic Synthesis
Author: William B. Motherwell
Publisher: Elsevier
Total Pages: 289
Release: 2013-10-22
Genre: Science
ISBN: 0080924956

Written for both the experienced practitioner and the newcomer, this book provides essential guidance to the practical aspects of free radical chain reactions. The book presents tried and tested synthetic schemes as well as a selection of recently developed methods describing rationally designed, highly efficient syntheses giving high yield interconversions of functional groups and carbon*b1carbon bond formation under mild, neutral conditions. Written by two experienced practitioners in the field, this volume explodes the myth that free radicals are highly reactive, non-selective intermediates. Contains an extensive introduction discussing principles, advantages, and disadvantages of radical chain reactions Demonstrates functional group interconversions by radical chain reactions Lists carbon*b1carbon bond formations Presents inter- and intramolecular radical chain reactions Includes many examples and experimental details selected by experienced practitioners in this field

Inhibition of Chain Reactions

Inhibition of Chain Reactions
Author: V V Azatyan
Publisher: CRC Press
Total Pages: 360
Release: 2000-07-06
Genre: Science
ISBN: 9789069940021

This text explores nonbranching reactions, including in-depth information on the inhibitors of free radical polymerisation and the mechanisms of antioxidants on oxidationprocesses. Auto-initiated chain reactions are also explored, with detailed descriptions on the kinetics, mechanisms, and inhibition of the autoxidation of organic compounds, A special chapter deals with the synergism of antioxidant actions. The theory of chain-branching reactions is investigated, and a large amount of new experimental data concerning the use of chemical additives to regulate combustion processes is also presented, including the mode of chain thermal explosion.

Comprehensive Organic Reactions in Aqueous Media

Comprehensive Organic Reactions in Aqueous Media
Author: Chao-Jun Li
Publisher: John Wiley & Sons
Total Pages: 435
Release: 2007-06-04
Genre: Science
ISBN: 0470131438

An extensive update of the classic reference on organic reactions in water Published almost a decade ago, the first edition has served as the guide for research in this burgeoning field. Due to the cost, safety, efficiency, and environmental friendliness of water as a solvent, there are many new applications in industry and academic laboratories. More than forty percent of this extensively updated second edition covers new reactions. For ease of reference, it is organized by functional groups. A core reference, Comprehensive Organic Reactions in Aqueous Media, Second Edition: * Provides the most comprehensive coverage of aqueous organicreactions available * Covers the basic principles and theory and progresses to applications * Includes alkanes, alkenes, aromatics, electrophilic substitutions, carbonyls, alpha, beta-unsaturated carbonyls, carbon-nitrogen bonds, organic halides, pericyclic reactions, photochemical reactions, click chemistry, and multi-step syntheses? * Provides examples of applications in industry This is the premier reference for chemists and chemical engineers in industry or research, as well as for students in advanced-level courses.

The Chemistry of Radical Polymerization

The Chemistry of Radical Polymerization
Author: Graeme Moad
Publisher: Elsevier
Total Pages: 667
Release: 2006
Genre: Science
ISBN: 0080442889

This book commences with a general introduction outlining the basic concepts of radical polymerization. This is followed by a chapter on radical reactions that is intended to lay the theoretical ground-work for the succeeding chapters on initiation, propagation and termination.

New Aspects in Phosphorus Chemistry V

New Aspects in Phosphorus Chemistry V
Author: Jean-Pierre Majoral
Publisher: Springer Science & Business Media
Total Pages: 300
Release: 2005
Genre: Biochemistry
ISBN: 9783540224983

Phosphorus chemistry is a diverse field and this volume focuses on new developments of "old themes" with different approaches and ideas, state of the art for two topics of general interest, and the emerging fields of research. This volume only describes in part the huge number of original papers on phosphorus-related topics.

The Art of Writing Reasonable Organic Reaction Mechanisms

The Art of Writing Reasonable Organic Reaction Mechanisms
Author: Robert B. Grossman
Publisher: Springer Science & Business Media
Total Pages: 371
Release: 2007-07-31
Genre: Science
ISBN: 0387954686

Intended for students of intermediate organic chemistry, this text shows how to write a reasonable mechanism for an organic chemical transformation. The discussion is organized by types of mechanisms and the conditions under which the reaction is executed, rather than by the overall reaction as is the case in most textbooks. Each chapter discusses common mechanistic pathways and suggests practical tips for drawing them. Worked problems are included in the discussion of each mechanism, and "common error alerts" are scattered throughout the text to warn readers about pitfalls and misconceptions that bedevil students. Each chapter is capped by a large problem set.